CobaltMaghrebV1, Main, Exploration, bibRecord, 000183

1-Phenylpiperazine-1,4-diium tetrachloridocobalt(II)

Identifieur interne : 000183 ( Main/Exploration ); précédent : 000182; suivant : 000184

1-Phenylpiperazine-1,4-diium tetrachloridocobalt(II)

Auteurs : Abdelhamid Chiheb Dhieb [Tunisie] ; Daron E. Janzen [États-Unis] ; Mohamed Rzaigui [Tunisie] ; Wajda Smirani Sta [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.

RBID : PMC:3998532

Abstract

In the title molecular salt, (C₁₀H₁₆N₂)[CoCl₄], the piperazine ring of the phenylpiperazine dication adopts a chair conformation and the phenyl ring occupies an equatorial orientation. In the tetrachloridocobaltate(II) dianion, the Co—Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N—H⋯Cl hydrogen bonds, generating [001] chains.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998532

DOI: 10.1107/S1600536814005790
PubMed: 24826100
PubMed Central: 3998532

Affiliations:

Tunisie, États-Unis

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Serveur d'exploration sur le cobalt au Maghreb

1-Phenylpiperazine-1,4-diium tetrachloridocobalt(II)

1-Phenylpiperazine-1,4-diium tetrachloridocobalt(II)

Source :

Abstract

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	Serveur d'exploration sur le cobalt au Maghreb
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Serveur d'exploration sur le cobalt au Maghreb

1-Phenyl­piperazine-1,4-diium tetra­chlorido­cobalt(II)

1-Phenyl­piperazine-1,4-diium tetra­chlorido­cobalt(II)

Source :

Abstract

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1-Phenylpiperazine-1,4-diium tetrachloridocobalt(II)

1-Phenylpiperazine-1,4-diium tetrachloridocobalt(II)